Войдите в систему

Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra. Schrödinger described electrons as three-dimensional stationary waves, or wavefunctions, represented by the Greek letter psi, ψ

A few years later, Max Born proposed an interpretation of the wavefunction ψ that is still accepted today: Electrons are still particles, and so the waves represented by ψ are not physical waves but, instead, are complex probability amplitudes. The square of the magnitude of a wavefunction ∣ψ2 describes the probability of the quantum particle being present near a certain location in space. This means that wavefunctions can be used to determine the distribution of the electron’s density with respect to the nucleus in an atom. In the most general form, the Schrödinger equation can be written as:

Eq1

where, Ĥ is the Hamiltonian operator, a set of mathematical operations representing the total energy (potential plus kinetic) of the quantum particle (such as an electron in an atom), ψ is the wavefunction of this particle that can be used to find the special distribution of the probability of finding the particle, and  E  is the actual value of the total energy of the particle.

Schrödinger’s work, as well as that of Heisenberg and many other scientists following in their footsteps, is generally referred to as quantum mechanics.

The quantum mechanical model describes an orbital as a three-dimensional space around the nucleus within an atom, where the probability of finding an electron is the highest. 

This text is adapted from Openstax, Chemistry 2e, Section 6.3: Development of Quantum Theory.

Теги
Quantum Mechanical Model Of An AtomElectronParticle natureWave naturePositionVelocityComplementary PropertiesKinetic EnergyElectron Probability DensityEnergyNucleusSchr dinger EquationWave FunctionWave FunctionsElectron Probability DensityDotsUnit VolumePositionPlot

Из главы 7:

article

Now Playing

7.9 : The Quantum-Mechanical Model of an Atom

Electronic Structure of Atoms

41.3K Просмотры

article

7.1 : The Wave Nature of Light

Electronic Structure of Atoms

47.7K Просмотры

article

7.2 : The Electromagnetic Spectrum

Electronic Structure of Atoms

52.0K Просмотры

article

7.3 : Interference and Diffraction

Electronic Structure of Atoms

29.0K Просмотры

article

7.4 : Photoelectric Effect

Electronic Structure of Atoms

28.9K Просмотры

article

7.5 : The Bohr Model

Electronic Structure of Atoms

48.4K Просмотры

article

7.6 : Emission Spectra

Electronic Structure of Atoms

48.0K Просмотры

article

7.7 : The de Broglie Wavelength

Electronic Structure of Atoms

25.1K Просмотры

article

7.8 : The Uncertainty Principle

Electronic Structure of Atoms

22.6K Просмотры

article

7.10 : Quantum Numbers

Electronic Structure of Atoms

33.9K Просмотры

article

7.11 : Atomic Orbitals

Electronic Structure of Atoms

32.5K Просмотры

article

7.12 : The Pauli Exclusion Principle

Electronic Structure of Atoms

32.2K Просмотры

article

7.13 : The Energies of Atomic Orbitals

Electronic Structure of Atoms

23.4K Просмотры

article

7.14 : The Aufbau Principle and Hund's Rule

Electronic Structure of Atoms

40.6K Просмотры

article

7.15 : Electron Configuration of Multielectron Atoms

Electronic Structure of Atoms

36.2K Просмотры

JoVE Logo

Исследования

Образование

О JoVE

Авторские права © 2025 MyJoVE Corporation. Все права защищены